QuestionApril 24, 2025

Order the following molecules from lowest to highest boiling points Cl_(2) NH_(3) CH_(3)Cl SeF_(4) Cl-1 (CH_(3))_(3)CH H_(2)O CH_(3)OH

Order the following molecules from lowest to highest boiling points Cl_(2) NH_(3) CH_(3)Cl SeF_(4) Cl-1 (CH_(3))_(3)CH H_(2)O CH_(3)OH
Order the following molecules from lowest to highest boiling points
Cl_(2) NH_(3) CH_(3)Cl SeF_(4) Cl-1 (CH_(3))_(3)CH H_(2)O CH_(3)OH

Solution
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Answer

Cl_2 < (CH_3)_3CH < CH_3Cl < NH_3 < CH_3OH < SeF_4 < H_2O < Cl^- Explanation 1. Identify Intermolecular Forces Cl_2: Dispersion forces. NH_3: Hydrogen bonding and dipole-dipole. CH_3Cl: Dipole-dipole and dispersion. SeF_4: Dipole-dipole and dispersion. Cl^-: Ionic interactions. (CH_3)_3CH: Dispersion forces. H_2O: Strong hydrogen bonding. CH_3OH: Hydrogen bonding and dipole-dipole. 2. Compare Molecular Weights Generally, higher molecular weight leads to higher boiling points due to increased dispersion forces. 3. Rank Based on Forces and Weight Consider both intermolecular forces and molecular weights to rank the boiling points.

Explanation

1. Identify Intermolecular Forces<br /> $Cl_2$: Dispersion forces. $NH_3$: Hydrogen bonding and dipole-dipole. $CH_3Cl$: Dipole-dipole and dispersion. $SeF_4$: Dipole-dipole and dispersion. $Cl^-$: Ionic interactions. $(CH_3)_3CH$: Dispersion forces. $H_2O$: Strong hydrogen bonding. $CH_3OH$: Hydrogen bonding and dipole-dipole.<br /><br />2. Compare Molecular Weights<br /> Generally, higher molecular weight leads to higher boiling points due to increased dispersion forces.<br /><br />3. Rank Based on Forces and Weight<br /> Consider both intermolecular forces and molecular weights to rank the boiling points.
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