QuestionJuly 20, 2025

The two different compounds [Cu(NH_(3))_(4)][Fe(CN)_(4)(H_(2)O)_(2)] and [Cu(CN)_(4)] [Fe(NH_(3))_(4)(H_(2)O)_(2)] are examples of: optical isomers linkage isomers coordination isomers ionization isomers geometric isomers

The two different compounds [Cu(NH_(3))_(4)][Fe(CN)_(4)(H_(2)O)_(2)] and [Cu(CN)_(4)] [Fe(NH_(3))_(4)(H_(2)O)_(2)] are examples of: optical isomers linkage isomers coordination isomers ionization isomers geometric isomers
The two different compounds [Cu(NH_(3))_(4)][Fe(CN)_(4)(H_(2)O)_(2)] and [Cu(CN)_(4)]
[Fe(NH_(3))_(4)(H_(2)O)_(2)] are examples of:
optical isomers
linkage isomers
coordination isomers
ionization isomers
geometric isomers

Solution
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Answer

coordination isomers Explanation 1. Identify the type of isomerism Coordination isomers occur when there is an exchange of ligands between the cationic and anionic parts of a coordination compound. 2. Analyze given compounds In [Cu(NH_{3})_{4}][Fe(CN)_{4}(H_{2}O)_{2}], copper is coordinated with ammonia, and iron is coordinated with cyanide and water. In [Cu(CN)_{4}][Fe(NH_{3})_{4}(H_{2}O)_{2}], copper is coordinated with cyanide, and iron is coordinated with ammonia and water. 3. Determine the isomerism type The two compounds show an exchange of ligands (NH₃ and CN⁻) between the metal centers (Cu and Fe), indicating coordination isomerism.

Explanation

1. Identify the type of isomerism<br /> Coordination isomers occur when there is an exchange of ligands between the cationic and anionic parts of a coordination compound.<br /><br />2. Analyze given compounds<br /> In $[Cu(NH_{3})_{4}][Fe(CN)_{4}(H_{2}O)_{2}]$, copper is coordinated with ammonia, and iron is coordinated with cyanide and water. In $[Cu(CN)_{4}][Fe(NH_{3})_{4}(H_{2}O)_{2}]$, copper is coordinated with cyanide, and iron is coordinated with ammonia and water.<br /><br />3. Determine the isomerism type<br /> The two compounds show an exchange of ligands (NH₃ and CN⁻) between the metal centers (Cu and Fe), indicating coordination isomerism.
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