QuestionApril 21, 2025

Which of the following is NOT true? A reaction will be nonspontaneous at all temperatures if Delta H is positive and Delta S is negative the process of converting a substance from solid to liquid is characterized by a decrease in entropy, the entropy for any substance increases with temperature For the process of vaporization, Delta Sgt 0

Which of the following is NOT true? A reaction will be nonspontaneous at all temperatures if Delta H is positive and Delta S is negative the process of converting a substance from solid to liquid is characterized by a decrease in entropy, the entropy for any substance increases with temperature For the process of vaporization, Delta Sgt 0
Which of the following is NOT true?
A reaction will be nonspontaneous at all temperatures if Delta H is positive and Delta S is negative
the process of converting a substance from solid to liquid is characterized by a
decrease in entropy,
the entropy for any substance increases with temperature
For the process of vaporization, Delta Sgt 0

Solution
4.1(136 votes)

Answer

The process of converting a substance from solid to liquid is characterized by a decrease in entropy. Explanation 1. Analyze each statement 1. A reaction is nonspontaneous at all temperatures if \Delta H is positive and \Delta S is negative. This is true because the Gibbs free energy change \Delta G = \Delta H - T\Delta S will always be positive. 2. The process of converting a substance from solid to liquid is characterized by an increase in entropy, not a decrease, as the molecules have more freedom of movement in the liquid state. 3. The entropy for any substance increases with temperature. This is true because increased temperature generally increases molecular motion and disorder. 4. For the process of vaporization, \Delta S > 0. This is true because vaporization involves a transition from a more ordered liquid state to a less ordered gaseous state.

Explanation

1. Analyze each statement<br /> 1. A reaction is nonspontaneous at all temperatures if $\Delta H$ is positive and $\Delta S$ is negative. This is true because the Gibbs free energy change $\Delta G = \Delta H - T\Delta S$ will always be positive.<br /> 2. The process of converting a substance from solid to liquid is characterized by an increase in entropy, not a decrease, as the molecules have more freedom of movement in the liquid state.<br /> 3. The entropy for any substance increases with temperature. This is true because increased temperature generally increases molecular motion and disorder.<br /> 4. For the process of vaporization, $\Delta S > 0$. This is true because vaporization involves a transition from a more ordered liquid state to a less ordered gaseous state.
Click to rate:

Similar Questions